基于剛性共軛富烯配體及不對稱1，3，4-Oxadiazole雜環(huán)橋連有機配體的有機-無機配位聚合物的合成及性質研究.pdf

1、山東師范大學碩士學位論文基于剛性共軛富烯配體及不對稱1，3，4Oxadiazole雜環(huán)橋連有機配體的有機無機配位聚合物的合成及性質研究姓名：王鵬申請學位級別：碩士專業(yè)：有機化學指導教師：董育斌20040428AbstractThechemistryoforganicinorganiccoordinationpolymershasrecentlybecomeareaofincreasinginterestSelfassemblyoforg

2、anicligandsandinorganicmetalionsisoneofthemostefficientandwidelyusedapproachesfortheconstructionoforganic4norganiccompositematerialsInthethesis，aseriesofnewtyperigidconjugatednanometersizedfulveneHgandsweresynthesized，fu

3、rthermore，cyclopenta[d][I2]pyridazinecontainingligandswereobtainedbythereactionofthe14diketonegrouponthosefulveneligandswithArNHNH2ThecoordinationchemistryofbothnewtypesofligandswithtransitionmetalionswereinvestigatedIna

4、ddition，twounsymmetrical1，3，4Oxadiazolecontainingligandshavebeensynthesizedandtheircoordinationchemisltrywithcuc【11andAg(I)wasinvestigatedTotally12newcoordinationpolymerswerepreparedbysolutionreactionsandfullycharacteriz

5、edbyIRelementalanalysisandsingle—crystalXraydiffraction1SevennewAgcontainingcoordinationpolymericcompoundsgeneratedfromthenewfulveneligandswitIlAgCl04H20andAgSbF6havebeensynthesized“Ag(L1)C104’35(C6H6)(1)，Ag(L2)2SbF6(2)，

6、Ag(L2hSbF6(3)，Ag(Lt)SbFt“H20(4)：，[AgffLlI)(礦一c6H6XH20)](CIO&’(C6H6)1(H20)05(5)，JlAg(L11)]SbF6‘soivate(6)，IIAg(L11)](SbFt)2‘2C6H6’CH2C12(7)TheirSinglecrystalstructuresandluminescentpropertieswereinvestigatedinthesolidstat

7、e2TwonewHbondedonedimensionalsupramolecularcomplexes，namelyCo(L)z(C2IIsOH)2(8：L2L2，9：L=L6)“weresynthesizedbythereactionsofCoOAcwithfulveneHgandL2andL6respectivelySinglecrystalstructuresandluminescentpropertieswereinvesti

8、gatedinthesolidstate3TwonewCu(IDcontainingcoordinationpolymericcompoundsbasedonunsymmetrical1，3，4一Oxadiazolecontainingiigands(L17)，namely【(Cu2(OAc)4)3Cu(OAc)z(L17)4]‘2CH30H2H20(10)and[Cu(L17)S042H201’H20(11)wereobtainedT

9、hefirstAg(I)containingorganometalliccoordinationpolymernamelyAg(L19)OTf(12)，wasalsosynthesizedbyunsymmetricaloxadiazolecontainingligandLI9Theirsinglecrystalstructuresandluminescentpropertieswereinvestigatedinthesolidstat