乒乓球拍用水性黏合劑的制備與應用研究.pdf

1、安徽理工大學碩士學位論文乒乓球拍用水性黏合劑的制備與應用研究姓名：王斌申請學位級別：碩士專業(yè)：應用化學指導教師：邢宏龍20110603安徽理工大學碩士論文摘要AbstractWaterbasedadhesivefortabletennisracketWaspreparedwithmethylmethacrylate(MMA)，butylacrylate(BA)，vinylacetate(VAc)asmonomers，sodiumdode

2、cylsulfate(SDS)andpolyoxyethylenenonylphenylether(OP一10)asemulsifier，potassiumpersulphate(KPS)asinitiator，bysemi—continuouscoreshellemulsionpolymerizationEffectofemulsifier，initiatorandreactiontemperatureonthestability，c

3、onversionrate，particlesizeofemulsionWasresearchedandcharacterizedbyTEM，particlesizeanalyzerandSOonTheresultsshowedthat：amountofemulsifieraccountedfor30％ofthesystemmassratioofSDSandOP10Was1：3，amountofinitiatorWasO5％ofthet

4、otalmassofmonomermassratioofmonomerIand11was3：7，reactiontimeWas2OhreactiontemperatureWas8085“C，adhesiveemulsionhadgoodstability，theaveragediameteroflatexparticlesWasabout150nm，andconverSionrateofmonomerwasover96％Waterbas

5、edadhesiveWasformedfilmEffectofreactionmonomercross—linkingmonomerandfunctionalmonomeronthetensilestrengthhardnessandwaterabsorptionofadhesivefilmwasstudiedandcharacterizedbyhardnesstesteruniversaltestingmachine，DSC，TGan

6、dSOonTheresultsshowedthat：massratioofmonomerI(MMA：VAc)andmonomerII(BA：VAc)were20：10，50：20，massratioofthecrosslinkingmonomerethyleneglycoldimethacrylate(EGDMA)anddivinylbenzene(DVB)was2：1，amountofacrylicacid(AA)was3O％thet

7、otalmassofmonomertheadhesivefilmWascontinuous、transparent，andhadacertaindegreeofhydrophilicitythepencilhardnessandtensilestrengthwere2H，639MPaWaterbasedadhesivewasappliedtobondingthefloorandrubberfortabletennisbatEffecto

8、fcomonomercross—linkingmonomerandcuringtemperatureonthe1800strippingtimeWasresearchedandcharacterizedbypeeloffintensitytesterTheresultsshowed：massratioofMMAandVAc，BAandVAc，EGDMAandDVBwere20：10，50：20，2：1respectivelyandcur

9、ingtemperatureWas50“C，theadhesivehadlonger1800strippingtimeandexcellentbondingstrength。Figure[twentyfive]Table[eighteen]Reference[eightytwo】Keywords：adhesive，waterbased，preparationtabletennisracket，applicationChinesebook