功能性有機(jī)-無機(jī)雜化多金屬氧酸鹽研究.pdf

1、安徽大學(xué)碩士學(xué)位論文功能性有機(jī)無機(jī)雜化多金屬氧酸鹽研究姓名：周愛民申請學(xué)位級別：碩士專業(yè)：無機(jī)化學(xué)指導(dǎo)教師：田玉鵬2002.6.1———————————————————————————————————————————————————————一旦AbstractBasedontheinvestigationsoftremendousliteratures，Wefindthatorganicinorganichybridmaterialsw

2、hicharcvitaIvarietiesofmateriaIscience，arefcrtilefieldandhaveattractiveappliedvaluesUponthat，thistreatisefallstodoingworksrunningaRerthishotpointFourchaptersarecomprisedinthisthesis：Chaptcrl：givestheoutlineoforganicinorg

3、anichybridmaterialsareaThroughinvestigationandgeneralization，Weknowthatpolyoxometalatebasedorgaic—inorganichybridmaterials，whichhavesovailOUSstructuresastodesignandtailermoleculeseasilyhavebothfunctionalpropertiesoforgan

4、icmoietiesandthermalstabilizationofinorganicmoietiesChapter2：inrmducassynthesismethodsofaserialoforganicinorganichybridpolyoxomcmlatcsThen。employingIRspectrum，elementalanalysisandTGA，wegivethisserialofcompoundsnecessaryd

5、eterminationsEighteencompoundshavebeensynthesizedinthisthesis，amongwhichSeV口IcompoundsareobitsInthischapterweobtainthree盯ys協(xié)lstructuresofcorrespondingcompoundsandconcludethroughcomparisonthatplanepmportygoesbadwithlength

6、ofsubstitutesattachingtothecationsChapter3：hassystematicstudiesofopticalpropertiesofthisserialcompoundsSuchmeasures粥electronslmctrom。fluorcsoencespcctrominsolutionandinsolid，twophotonabsorptionopticallimitingarcemployedi

7、nthesestudiesWefmdthatallofthesecompoundshavelishtexcitademittingproperiesandnonlinearabsorptionproperties砒di疵晴呲ext∞tsAllofthispropertieslayoutappliedprospectsoftheminoptelectronfunctionalmaterialsareaChapter4：Through蛐fi

8、onsofcyclicvolmmmeUyanddi最pulsevoltammetrytheirelectroctmmicalpmp礎(chǔ)s骶studiedWefindthateachofthemhasniceelectrochemicalpropertiesandreversibleredoxpropertiesWhereaRerweobtainsomebenetici曩lconclusionsviacomparisonand鋤lysisI

9、naweIrd。thistreatiseexpandsitssightinextensivearea，employsorganicinorganicstrategyWehaveacqIjlilcdaserialofcompoundswithscientificandapplyingvalues，whichgivenovelandbeneficialgropingtotheresearchoforganicinorganichybridm