大學(xué)生的畢業(yè)論文石油化工類的

1、I兩種工藝條件下渣油加氫產(chǎn)物對(duì)比研究 兩種工藝條件下渣油加氫產(chǎn)物對(duì)比研究郭靖蘭州交通大學(xué)摘 要本課題配合撫順石油化工研究院渣油加氫處理技術(shù)開發(fā)工作，針對(duì)同一渣油經(jīng)兩種加氫工藝加工后的生成油，進(jìn)行物化性質(zhì)和八組分分離等研究。即將原料油及加氫處理油的正庚烷可溶物進(jìn)入色譜柱分離，得到飽和烴、輕芳烴、中芳烴、重芳烴、輕膠質(zhì)、中膠質(zhì)、重膠質(zhì)和瀝青質(zhì)八組分。借助元素分析儀、化學(xué)熒光定硫儀、化學(xué)發(fā)光定氮儀等對(duì)原料油、加氫處理油及八組分的氫、碳、硫、

2、氮含量、金屬含量等性質(zhì)進(jìn)行測(cè)定，給出原料油及加氫生成油組成的詳細(xì)信息，為比較兩種工藝的優(yōu)缺點(diǎn)、催化劑選擇、工藝流程選擇等提供依據(jù)。結(jié)果表明：硫、氮和金屬等雜原子主要集中在較重的組分中。硫主要集中在芳烴和膠質(zhì)組分中，其中重芳烴和輕膠質(zhì)中硫的含量最高，重芳烴中氮含量較前幾個(gè)組分明顯增多，重膠質(zhì)氮含量最高。研究結(jié)果還表明：在脫金屬段，工藝 A 的脫釩和脫鎳程度都比工藝 B 要大，工藝 A 的脫釩、脫鎳效果更佳；在脫硫、氮段，硫、氮的脫除率工藝

3、 B 明顯高于工藝 A，工藝 B 的脫硫、氮效果更佳。渣油固定床加氫處理是合理利用渣油的最為有效的手段之一。渣油轉(zhuǎn)化為更有價(jià)值的產(chǎn)物取決于對(duì)其組成和性質(zhì)的認(rèn)識(shí)，以及原料油與加氫處理油之間的關(guān)聯(lián)關(guān)系的研究和轉(zhuǎn)化工藝的選擇。IIIComparative study of the product of residue hydrotreating by two different processesTong Beizhen（Industry A

4、nalysis 0501，Institute of Petrochemical Technology，Liaoning Shihua University，F(xiàn)ushun Liaoning，113001）AbstractCooperating with FRIPP working on development of residue fixed-bed hydrotreating technologies, various post-pro

5、cessing oils were obtained by two different processes, and the physical and chemical properties of the post-processing oils were investigated to compare the processes. Feedstock and fixed-bed residue hydrotreating produc

6、t were dissolved by n-heptane, and were further separated into eight components. The eight components were saturates, light aromatics, middle aromatics, heavy aromatics, light resins, middle resins, heavy resins and asph

7、altene separately. These separation schemes could quantify the components, and prepare for later analyses.With the help of modern instruments, the information of the composition and physical chemistry properties of the s

8、amples were provided. Metal content was determined by ICP-AES; Sulfur was detected by ultraviolet fluorimetry, nitrogen by chemiluminescence. Those information and data they offered can provide necessary data for

9、 further study on group composition and chemical composition.The results show that heteroatom concentrates in heavier component. Sulfur mainly concentrates in aromatics and resins of eight components. Sulfur content is

10、highest in heavy aromatics and light resins of eight components. Nitrogen content increases in evidence in heavy aromatics, and is highest in heavy resins. The results also demonstrate that at the stage of UFR, Art A rem