二烷硫基亞甲基丙二酸異核配合物的合成、結構及性質研究.pdf

1、學校代碼：—102—00分類號：06__22⑧研究生學號：—1020020—0421082密級：五東牡拇予葒大孽碩士學位論文二烷硫基亞甲基丙二酸異核配合物的合成、結構及性質研究Synthesis，StructureandPerformanceoftheheteronuclearComplexeswithAlkylenedithiomethyleneMalonicAcidAsCoordinationAgent作者：凌素芹指導教師學科專業(yè)研

2、究方向學伉類型邵允副教授有機化學有機合成學歷碩士東北師范大學學位評定委員會2007年5月AbstractAsthecalboxylcomplexeshavespecialpropertiesanddiversiformstructure，thesecomplexeshaveextensivepotentialapplicationinmanyfieldssuchasmagnetics，catalystmoleculecarriers，g

3、asstorageandergonomicsSothestudyofthecomplexesandcoordinationpolymersenrichedthestudyoftheoriesThesecompoundshavethepotentialapplicationinmanyfieldsInthisstudyaldyl【encdithiomethyleneMalonicacidactsasthemaincoordinationa

4、gentsandcompoundironionhavebeensynthesizedbytheme紐qsofsolutionAsaresult，theIDpolymerisobtainedThen3doordinationcomplexesandpolymershavebeendesignedandsynthesizedinthislDpolymerThesecompoundshavebeencharacterizedbyXraysin

5、glecrystaldiffractionanalysis，andsomepropertiesofthemhavebeenhavebeentestedandanalyzed1IncoordinationcompoundNa[Fe(HDYM)2(DYM)]’10H20(IIDYM=2一(1，3dithiolan2ylidene)malonicacidThelocalenvironmentofironexhibitsdistortedoct

6、ahedroncoordinatedwithtwocarboxylatooxyenatomsfzonHdymaEachdymwithF“II)ionparticipatesinformingsixmemberedchealthingrin黟。ThereexistsbondinteractiongsamongllallillHlandOxygenatomstiomcoordinatewatermoleculeandBncoordinate

7、dealboxylategroups，exhibitsanamorphieoctahedrom2TransitionmetaldinuclealcomplexesC03Fe2(dyma)6(H20)14]’7H20(Hdyma2【l，3】dithiolan2ylidenernalonicacimThelocalmetalionofeachadoptsasixcoordinatedexhibitsdistortedoctahedromFe

8、(2)coordinationtotwofiveoxyenatomsoftwocheatingealboxylategroupsoftwoHdymaligandscreatedasixmemberedehealthingringsCoO)ionandCo(2)ion麗thadymaadoptsficarboxylobandcompoundedthencompoundwithfiveOxygenatomsfromcoordinatewat

9、erCo(3)ionwiththeothertwohymacompoundbydearboxylobondthencompoundwithfiveOxygenatomsfromcoordinatewater3f[NaFe2Mn2(HdymaXdyma)5(H20)10]‘6H20nislieal(1D)coordinationpolymerbytheconnectionofO(12)ThearrangenentofManganeseio

10、nisW：FermmionandmanganeseioncoordinatedwithdymabyseveradaprochesSuchas15bidentatechealth13bidentatcchealthandandsoonTheionsoffeandManganeseionandFcrmmionalehexdcoordnatedThelOCalenvironmentofironexhibitsdistortedoctahedr

11、om4ThelocalmetalionsFc(11andFe(2)ofthecalboxylcomplesx[Z_212Fe2(Hdyma)2(dyllla)4(I120)2]lOH20nalesixcoorinatall，andexhibitsdistortedoctahedronThlocalZincionsZn(1)andZn(2)alefourcoorinatell，eachZincionslinkedwithI_teorbox