電子電氣類專業(yè)畢業(yè)設(shè)計(jì)外文翻譯

1、<p><b>　　附錄一：外文原文</b></p><p>　　Super capacitors - An Overview</p><p>　　Key words: Electrostatic capacitor; Electrolytic capacitor; Ceramic capacitor; Electrical double layer cap

2、acitor; Super Capacitor</p><p>　　INTRODUCTION</p><p>　　This paper offers a concise review on the renaissance of a conventional capacitor to electrochemical double layer capacitor or super capaci

3、tor. Capacitors are fundamental electrical circuit elements that store electrical energy in the order of microfarads and assist in filtering. Capacitors have two main applications; one of which is a function to charge or

4、 discharge electricity. This function is applied to smoothing circuits of power supplies, backup circuits of microcomputers, and timer circui</p><p>　　An electrochemical capacitor (EC), often called a Super

5、capacitor or Ultra capacitor, stores electrical charge in the electric double layer at a surface-electrolyte interface, primarily in high-surface-area carbon. Because of the high surface area and the thinness of the doub

6、le layer, these devices can have very a high specific and volumetric capacitance. This enables them to combine a previously unattainable capacitance density with an essentially unlimited charge/discharge cycle life. The

7、oper</p><p>　　The concept of storing electrical energy in the electric double layer that is formed at the interface between an electrolyte and a solid has been known since the late 1800s. The first electrica

8、l device using double-layer charge storage was reported in 1957 by H.I. Becker of General Electric (U.S. Patent 2,800,616).Unfortunately, Becker’s device was impractical in that, similarly to a flooded battery, both elec

9、trodes needed to be immersed in a container of electrolyte, and the device was never co</p><p>　　Becker did, however, appreciate the large capacitance values subsequently achieved by Robert A. Rightmire, a c

10、hemist at the Standard Oil Company of Ohio (SOHIO), to whom can be attributed the invention of the device in the format now commonly used. His patent (U.S. 3,288,641), filed in 1962 and awarded in late November 1966, and

11、 a follow-on patent (U.S. Patent 3,536,963) by fellow SOHIO researcher Donald L. Boos in 1970, form the basis for the many hundreds of subsequent patents and journal arti</p><p>　　This technology has grown i

12、nto an industrywith sales worth severalhundred million dollars per year. It is an in dustry that is poised today for rapid growth in the near term with the expansion of power quality needs and emerging transportation app

13、lications.</p><p>　　Following the commercial introduction of NEC’s Super Capacitor in 1978, under licence from SOHIO, EC have evolved through several generations of designs. Initially they were used as back-

14、up power devices for v is for cells ranging in size from small millifarad size devices with exceptional pulse power performance up to devices rated at hundreds of thousands of farads, with systems in some applications op

15、erating at up to 1,500 volts. The technology is seeing increasingly broad use, replacing batt</p><p>　　Early ECs were generally rated at a few volts and had capacitance values measured from fractions of fara

16、ds up to several farads. The trend today in some cases and in others complementing their performance.</p><p>　　The third generation evolution is the electric double layer capacitor, where the electrical char

17、ge stored at a metal/electrolyte interface is exploited to construct a storage device. The interface can store electrical charge in the order of Farad. The main component in the electrode construction is activated carbo

18、n. Though this concept was initialized and industrialized some 40 years ago, there was a stagnancy in research until recent times; the need for this revival of interest arises due to t</p><p>　　Figure 1. Sch

19、ematic presentation of electrostatic capacitor, electrolytic capacitor and electrical double layer capacitor.</p><p>　　EDLCs, however suffer from low energy density. To rectify these problems, recently resea

20、rchers try to incorporate transition metal oxides along with carbon in the electrode materials. When the electrode materials consist of transition metal oxides, then the electrosorption or redox processes enhance the val

21、ue of specific capacitance ca. 10 -100 times depending on the nature of oxides. In such a situation, the EDLC is called as super capacitor or pseudo capacitor . This is the fourth generation c</p><p>　　2. EX

22、PERIMENTAL PART</p><p>　　The invention of Leiden jar in 1745 started the capacitor technology; since then, there has been tremendous progress in this field. In the beginning, capacitors are used primarily in

23、 electrical and electronic products, but today they are used in fields ranging from industrial application to automobiles, aircraft and space, medicine, computers, games and power supply circuits. Capacitors are made fro

24、m two metallic electrodes (mainly Si) placed in mutual opposition with an insulating material (die</p><p>　　C = S/d (1)</p><p>　　where C(F) is the electrostatic

25、capacity, the dielectric constant of the dielectric, S (cm2) the surface area of the electrode and d (cm) the thickness of the dielectric. The charge accumulating principle can be described as follows: when a battery is

26、connected to the capacitor, flow of current induces the flow of electrons so that electrons are attracted to the positive terminal of the battery and so they flow towards the power source. As a result, an electron defici

27、ency develops at the positiv</p><p>　　The capacitance output of these silicon based capacitors is limited and has to cope with low surface-to volume ratios of these electrodes. To increase the capacitance, a

28、s per eq., one has to increase to or S and decrease; however the value is largely determined by the working voltage and cannot be tampered. When aiming at high capacitance densities, it is necessary to combine the mutua

29、l benefits achieved with a high permittivity insulator material and an increased effective surface area. With S</p><p>　　3. ELECTROLYTIC CAPACITORS</p><p>　　The next generation capacitors are th

30、e electrolytic capacitors; they are of Ta, Al and ceramic electrolytic capacitors. Electrolytic capacitors use an electrolyte as conductor between the dielectrics and an electrode. A typical aluminum electrolytic capacit

31、or includes an anode foil and a cathode foil processed by surface enlargement and or formation treatments. Usually, the dielectric film is fabricated by anodizing high purity Al foil for high voltage applications in bori

32、c acid solutions. The t</p><p>　　There are two types of tantalum capacitors commercially available in the market; wet electrolytic capacitors which use sulfuric acid as the electrolyte and solid electrolytic

33、 capacitors which use MnO2 as the solid electrolyte. Though the capacitances derived from both Ta and Al capacitors are the same, Ta capacitors are superior to Al capacitors in temperature and frequency characteristics.

34、For analog signal systems, Al capacitors produce a current-spike noise which does not happen in Ta capacit</p><p>　　The history of development of electrolytic capacitors which were mass produced in the past

35、as well as today is presented by S. Niwa and Y. Taketani . Many researchers try to improve the performance of these electrolytic capacitors by modifying the electrode or electrolyte. Generally, the increases in effective

36、 surface area (S) are achieved by electrolytic etching of aluminum substrate before anodization, but now it faces with the limit. It is also very difficult to decrease d because the d value</p><p>　　A cerami

37、c capacitor is a capacitor constructed of alternating layers of metal and ceramic, with the ceramic material acting as the dielectric. Multilayer ceramic capacitors (MLCs) typically consist of ~100 alternate layers of el

38、ectrode and dielectric ceramics sandwiched between two ceramic cover layers. They are fabricated by screen-printing of electrode layers on dielectric layers and co-sintering of the laminate. Conventionally, Ag-Pd is used

39、 as the electrode material and BaTiO3 is used as the</p><p>　　The other ceramic materials that have been identified and used are CaZrO3, MgTiO3, SrTiO3 etc. A typical 10 F MLC is a chip of size (3.2 x 1.6 x

40、1.5 mm). Mn, Ca, Pd , Ag etc are some of the other internal electrodes used. Linear dielectrics and antiferroelectrics based o strontium titante have been developed for high voltage disk capacitors. These are applicable

41、for MLCs with thinner layers because of their high coercive fields. One of the most critical material processing parameters is the degr</p><p>　　The other types of capacitors are film capacitors which use th

42、in polyester film and polypropylene film as dielectrics and meta-glazed capacitors which incorporate electrode plates made of film vacuum evaporated with metal such as Al. Films can be of polyester, polypropylene or poly

43、carbonate make. Also capacitors are specified depending on the dielectric used such as polyester film capacitor, polypropylene capacitor, mica capacitor, metallized polyester film capacitor etc.</p><p>　　4.

44、DOUBLE LAYER CAPACITORS</p><p>　　Electric/electrochemical double layer capacitor (EDLC) is a unique electrical storage device, which can store much more energy than conventional capacitors and offer much hig

45、her power density than batteries. EDLCs fill up the gap between the batteries and the conventional capacitor, allowing applications for various power and energy requirements i.e., back up power sources for electronic dev

46、ices, load-leveling, engine start or acceleration for hybrid vehicles and electricity storage generated fr</p><p>　　Figure 2. Charge storage mechanism of an EDLC cell under idle and charged conditions.</p

47、><p>　　Fig. 2 shows the mechanism of charge storage in an EDLC cell and Fig. 3 shows the configuration of an typical EDLC cell. There are two main types of double layer capacitors as classified by the charge st

48、orage mechanism: (i) electrical double-layer capacitor; (ii) electrochemical double layer capacitor or super/pseudo capacitor. An EDLC stores energy in the double-layer at the electrode/electrolyte interface, whereas the

49、 super capacitor sustains a Faradic reaction between the electrode and the el</p><p>　　Figure 3. Typical configuration of an EDLC cell</p><p>　　There are two general directions of interest. One

50、is the long term goal of the development of electrical propulsion for vehicles, and the other is the rapid growth of portable electronic devices that require power sources with maximum energy content and the lowest possi

51、ble size and weight.</p><p>　　5. CONCLUSIONS</p><p>　　According to a market survey by Montana, super capacitors are becoming a promising solution for brake energy storage in rail vehicles. The e

52、xpected technological development outside railway sector is also shown to be highly dynamic: diesel electric vehicles, catenary free operation of city light rail, starting system for diesel engines, hybrid-electric cars,

53、 industrial applications, elevators, pallet trucks etc. The time horizon expected for development is next 5 to 10 years. The main developmen</p><p>　　· long life time</p><p>　　· increa

54、se of the rated voltage</p><p>　　· improvements of the range of operating temperature</p><p>　　· increase of the energy and power densities</p><p>　　Very recently, hybrid

55、car is introduced in the market but it is turned to be very expensive and out of common man’s reach. Shortage and cost of fossil fuels already instigated alternate technologies viable for traction purposes. In such a sit

56、uation, EDLCs are also useful to store energy generated from non-conventional energy sources. A future possibility of service centers set up for EDLC supply similar to petrol (as on date) is not far as the main setbacks

57、in technology development may take a d</p><p><b>　　附錄二：外文譯文</b></p><p><b>　　超級(jí)電容器-概述</b></p><p>　　關(guān)鍵詞：靜電電容，電解電容器，陶瓷電容器，雙電層 ,電容器，超級(jí)電容器</p><p><

58、;b>　　引言</b></p><p>　　本文為電化學(xué)雙層電容器或超級(jí)電容器提供在一臺(tái)常規(guī)電容器，簡明的介紹新生的電化學(xué)雙電層電容器或超級(jí)電容器。電容器是存放電能并且協(xié)助過濾的根本電路元素。 電容器有二個(gè)主要應(yīng)用; 其中之一是充電或釋放電的作用。這個(gè)作用適用于電源平流濾波電路，微型計(jì)算機(jī)備用電路和利用期間充電或釋放電的定時(shí)器電路。其他是阻攔DC流程的作用。這個(gè)作用適用于提取或消滅特殊頻率的過濾

59、器。這是其中不可或缺的優(yōu)秀電路所需的頻率特性。電解電容是在充分的標(biāo)度商業(yè)化的下一代電容器。他們類似電池在細(xì)胞建筑，但是陽極和負(fù)極材料依然保持不變。他們是鋁，鉭和兩個(gè)陶瓷電容電解質(zhì)的地方與他們所使用的液體固體分離器/ 對(duì)稱的電極。</p><p>　　電化學(xué)電容器（EC），往往被稱為超級(jí)電容器或超級(jí)電容，存儲(chǔ)電荷的雙層電荷在1層表面電解質(zhì)界面，主要在高電位表面的碳。由于高電位表面是薄的雙重層，所以這些設(shè)備可以有一個(gè)

60、非常高的比和體積電容。這使得他們能夠結(jié)合以前無法實(shí)現(xiàn)的電容用無限的電荷密度/放電循環(huán)壽命。每單元的工作電壓，只受擊穿電位電解質(zhì)的影響，通常<1或“<3伏的每個(gè)細(xì)胞水性或有機(jī)電解質(zhì)分別。</p><p>　　該存儲(chǔ)的概念電力能源雙電層這是形成于界面之間的固體電解質(zhì)和一直都知道自19世紀(jì)末期。第一電氣設(shè)備使用雙層充電儲(chǔ)存在報(bào)告1957年H.I.貝克爾的通用電氣（美國專利2800616）。不幸的是，貝克爾的

61、設(shè)備是不切實(shí)際的，同樣一個(gè)充斥電池，電極都需要沉浸在一個(gè)容器電解質(zhì)，并且該設(shè)備從未商業(yè)化。</p><p>　　貝克爾那樣做了，但是隨后發(fā)現(xiàn)電容值已經(jīng)被標(biāo)準(zhǔn)石油化學(xué)家公司俄亥俄州（索奧）的羅伯特A賴特邁爾發(fā)明并且現(xiàn)在正在普遍使用。他的專利（美國3288641），在1962年年底提出并獲1966年11月，和一個(gè)后續(xù)專利（美國專利3536963）由資深研究員索奧唐納德L.布斯在1970年，形式為基礎(chǔ)隨后的專利和期刊數(shù)

62、百文章涉及ec技術(shù)的所有方面。</p><p>　　這項(xiàng)技術(shù)已經(jīng)發(fā)展成為一個(gè)行業(yè)銷售價(jià)值數(shù)1.0億美元每年。這是一個(gè)行業(yè)，這是今天并且準(zhǔn)備在不久的將來快速增長，長期與擴(kuò)張，需要的電能方面的專門人才。</p><p>　　隨著商業(yè)的引進(jìn)，NEC公司的超級(jí)電容器在1978年，根據(jù)從索奧那里拿到的牌照并且進(jìn)行了一些演變，通過了幾個(gè)世代的設(shè)計(jì)。起初，他們被用作后備電源裝置揮發(fā)性時(shí)鐘芯片和互補(bǔ)金屬氧

63、化物半導(dǎo)體（CMOS）的計(jì)算機(jī)記憶。但許多其他申請(qǐng)出現(xiàn)在之前的30年，包括便攜式無線通信，增強(qiáng)電能質(zhì)量的分布式發(fā)電系統(tǒng)，工業(yè)驅(qū)動(dòng)器電源，并高效率電動(dòng)車輛的能源儲(chǔ)存電動(dòng)車）和混合（混合電動(dòng)汽車）電動(dòng)汽車?？傮w而言，內(nèi)部細(xì)胞的獨(dú)特屬性經(jīng)常補(bǔ)充其他電力來源的弱點(diǎn)如電池和燃料電池。</p><p>　　早期的內(nèi)部電容一般在幾伏特額定電容值計(jì)算，并從分?jǐn)?shù)法拉達(dá)數(shù)的法拉。這個(gè)趨勢今天是在電容大小不等的小毫法，脈沖功率大小與特

64、殊設(shè)備性能高達(dá)百倍額定設(shè)備成千上萬的法拉，在一些應(yīng)用系統(tǒng)工作在高達(dá)1500伏。該技術(shù)是看到越來越廣泛的使用，取代在某些情況下，電池和其他補(bǔ)充會(huì)優(yōu)化他們的表現(xiàn)。</p><p>　　第三代演變是雙電層電容器，電荷被存放在金屬或電解質(zhì)接口被利用修建存貯設(shè)備。 接口可能存放電荷按~法拉的順序。主要成份在電極建筑是被激活的碳。 雖然這個(gè)概念初始化了并且工業(yè)化了大約40年前，研究停滯不前，直到最近時(shí)期; 由于對(duì)利益的需要復(fù)

65、蘇，如目前的需求增加電能儲(chǔ)存數(shù)碼電子設(shè)備、需要非常短的大功率脈沖可能由雙電層電容器履行的可植入的可移植的醫(yī)療設(shè)備和中止或者在車牽引的起動(dòng)操作。他們是補(bǔ)充電池，因?yàn)樗鼈兡芴峁└吖β拭芏群湍芰棵芏鹊汀?他們也有長于電池壽命和具有更高的能量密度比常規(guī)電容器。 這導(dǎo)致了電化學(xué)電容器連接與燃料電池或電池所謂的混合電荷存儲(chǔ)設(shè)備的新概念。這些電容器用炭和水電解質(zhì)的電極材料主要用于有機(jī)陽極和陰極，都可以商業(yè)化和日間使用。圖1是在他們的設(shè)計(jì)和建筑上提出描

66、述基本的區(qū)別的電容器的三種類型。</p><p>　　圖1.概要介紹靜電電容器、電解電容和雙層電容器。</p><p>　　EDLCs，受到低能源密度的影響。要矯正這些問題，研究員最近設(shè)法與在電極材料的碳一起加入過渡金屬氧化物。電極材料包括過渡金屬氧化物，當(dāng)電極材料組成的過渡金屬氧化物，然后電吸附或氧化還原加強(qiáng)過程的CA值比電容（10 -100倍取決于性質(zhì)）在這種情況下，EDLC被稱為su

67、per capacitor或pseudo capacitor。 這是第四代電容器。 超級(jí)電容器的表現(xiàn)同時(shí)結(jié)合二種能量儲(chǔ)存設(shè)備，即非法拉第負(fù)責(zé)在雙電層電容器電容和法拉第充電過程類似此案中的電池。用于內(nèi)存保護(hù)的EC設(shè)備的在電子電路市場年年是大約150-200百億美元。 對(duì)ECs的新的潛在的申請(qǐng)包括便攜式的電子設(shè)備市場、電能質(zhì)量市場，特別是由于分布式發(fā)電和低排放混合動(dòng)力汽車，公共汽車和卡車。有一些對(duì)和超級(jí)電容器有關(guān)的電容發(fā)表的評(píng)論。以目前的情

68、況，對(duì)電化學(xué)雙層電容器的演變從開始的簡單靜電電容器進(jìn)行總結(jié)。</p><p><b>　　2. 實(shí)驗(yàn)部分 </b></p><p>　　自1745年發(fā)明的萊頓瓶的電容技術(shù)開始;，從那以后，在這個(gè)領(lǐng)域有巨大的進(jìn)展。 一開始，電容器主要在電子和電子產(chǎn)品使用，但是他們今天擴(kuò)大了范圍，從工業(yè)應(yīng)用的領(lǐng)域到汽車、航空器和空間、醫(yī)學(xué)、計(jì)算機(jī)、比賽和電源電路。 電容器由在與一份絕緣材

69、料(電介質(zhì))的相互反對(duì)(主要Si)被做安置的二個(gè)金屬電極在積累的電荷電極之間。 與電容器相關(guān)的基本的等式是：</p><p>　　C = S/d (1)</p><p>　　C (F)是靜電容量、電介質(zhì)的介電常數(shù)，S(cm2)電極的表面和d(cm)電介質(zhì)的厚度。 原則上積累的電荷可以被描述如下： 當(dāng)電池被連接到電容器時(shí)，電流

70、流誘導(dǎo)流電子，使電子被吸引到電池的正極，因此他們流動(dòng)往電源。 結(jié)果，缺電子開發(fā)在正面邊，變得帶陽電荷，并且電子節(jié)余發(fā)展為消極邊，變得帶負(fù)電荷。 這電子流程繼續(xù)，直到二個(gè)電極之間的電位差變得相等與電池電壓。 因而電容器得到充電。一旦去除電池，電子從消極邊流動(dòng)到另一邊，缺失電子; 這個(gè)過程導(dǎo)致釋放。常規(guī)電容器產(chǎn)生電容在與50到400 V.各種各樣的材料的電壓范圍的0.1到1 F范圍內(nèi)例如紙(u1.2-2.6)，石蠟(u1.9-2.4)，聚乙

71、烯(u2.2-2.4)，多苯乙烯(u2.5-2.7)，硬橡膠(u2-3.5)，聚乙烯(3.1-3.2)，水硫磺（u，2-4.2)，塊滑石瓷(u6-7)， Al瓷(8-10)， mica（u，5-7)，并且被絕緣的礦物油(2.2-2.4)用來做電容器的電介質(zhì)。</p><p>　　這些芯片的輸出電容的電容是有限的，并且必須應(yīng)付表面對(duì)這些電極容量比率的低落。若需要增加電容。必須增加或S和減少; 然而使用電壓主要取決于

72、價(jià)值，并且不可能被篡改。當(dāng)針對(duì)高電容密度時(shí)，與高電容率絕緣體材料和增加的有效的表面結(jié)合達(dá)到的互惠是必要的。 使用Si作為基體材料，電化學(xué)蝕刻產(chǎn)生有效的表面積。這材料表面得到放大，是通過擴(kuò)大二個(gè)數(shù)量級(jí)并與未腐蝕表面比較。大孔硅電化學(xué)形成了用于制備高寬比傳統(tǒng)的電容。在增加具體電容的常規(guī)電容器的修改的研究工作也過程中。最近報(bào)道了大約30倍電容密度硅/鋁 /氧化鋅： Si電化學(xué)上被腐蝕成多孔一個(gè)的鋁電容器。 辨認(rèn)的另一個(gè)方式增加電極的表面將形成

73、正極被形成的氧化物(Al， Ta); 然而，陶瓷電容器是基于高介電常數(shù)而不是電極區(qū)域。</p><p><b>　　3. 電解電容</b></p><p>　　下一代電容器是電解電容; 他們是Ta、Al和陶瓷電解電容。 電解電容使用電解質(zhì)作為在電介質(zhì)和電極之間的指揮。一個(gè)典型的鋁電解電容器包括陽極箔及一個(gè)陰極箔，由其擴(kuò)大加工和表面處理或形成。通常情況下，電介質(zhì)薄膜制備

74、由高純度鋁陽極氧化膜在硼酸的解決方案為高電壓應(yīng)用。電介質(zhì)薄膜的厚度與鋁電解電容的使用電壓有關(guān)。在切開對(duì)具體大小根據(jù)設(shè)計(jì)規(guī)格之后，層壓制品組成陽極箔，陰極箔這是反對(duì)的陽極箔和電介質(zhì)膜分隔的中間人。陽極和陰極之間的箔，是提供分隔的一個(gè)元素。分隔元素電解質(zhì)在一個(gè)被覆蓋的金屬包裹，沒有電解電容的任何電子特征，直到完全地浸洗和安置，圓柱形金屬護(hù)套封裝封閉裝備結(jié)束。 此外，密封材料由有彈性橡膠制成，是一個(gè)被插入，被覆蓋的包裹，該套包和套包的開放式的

75、繪圖部分。電解鋁電容器為汽車、航空器、航天器、計(jì)算機(jī)、個(gè)人計(jì)算機(jī)顯示器、主板和其他電子主要使用提供電源。</p><p>　　有鉭電容器的二種類型在市場上買得到; 電解電容器，使用硫酸為電解液，使用二氧化錳作為固體電解質(zhì)。雖然電容Ta和Al電容器是相同的，但是Ta電容器在溫度和頻率特性上比Al電容器優(yōu)越。為模擬信號(hào)系統(tǒng)，鋁電容器產(chǎn)生電流尖峰噪音，但在Ta電容器不發(fā)生釘噪聲。 換句話說， Ta電容器為需要高穩(wěn)定性特

76、征的電路更受歡迎。Al電解電容的總?cè)澜缟a(chǎn)共計(jì)三十八億美元， 其中99%是濕型。固體鉭電解電容器不同，固體電解質(zhì)材料是有機(jī)物，一個(gè)功能聚合物和一個(gè)有機(jī)半導(dǎo)體。其次，MnO2是電解質(zhì)材料的組成，在電介質(zhì)層表面被合成，由電解綜合形成。在此以后，正極和負(fù)極電極組裝好，完成電子元件。 然而，這些電解電容電容在范圍0.1到10，電壓25F到50 V。</p><p>　　在電解電容的發(fā)展的歷史中，S. Niwa和Y. T

77、aketani提出大量生產(chǎn)。 許多研究員設(shè)法經(jīng)過修改電極或電解質(zhì)改進(jìn)這些電解電容的表現(xiàn)。通常，增加有效面積（S是實(shí)現(xiàn)鋁電解蝕刻基板），在陽極氧化，但現(xiàn)在它面臨限制。減少d也是非常難的，因?yàn)镈價(jià)值主要決定于工作電壓。這種情況下，綜合電介質(zhì)層數(shù)增量是形成可能會(huì)通過有價(jià)值化合物。MnO2的替換原先的電解質(zhì)是由于它有更高的傳導(dǎo)性; 芳香磺酸鹽離子作為充電補(bǔ)償?shù)膿诫s物離子。鋁固體電解電容器與蝕刻鋁箔為陽極，聚苯胺/鋁作為陰極和polypyrrro

78、le23作為電介質(zhì)。Masuda通過電化學(xué)正極化，迅速熄滅等得到了高電容Al鈦合金箔。 許多研究員嘗試了合金的另一個(gè)組合例如Al-Zr, Al-Si, Al-Ti, Al-Nb and Al-Ta綜合氧化膜。 Al2O3- (Ba0.5Sr0.5TiO3)和Al2O3- Bi4Ti3O12綜合氧化膜在低壓被銘刻的鋁芯的也被被認(rèn)為是類似的。Ta電解電容的Nb Ta Al也被嘗試了當(dāng)陽極材料。</p><p>　　一

79、個(gè)陶瓷電容，陶瓷電容與金屬構(gòu)造和層交替陶瓷材料作為電介質(zhì)的。陶瓷電容（通常由一層陶瓷與覆蓋層之間交替兩個(gè)電極和電介質(zhì)陶瓷夾著）。典型的多層陶瓷電容器(MLCs)包括電極和電介質(zhì)陶瓷。他們通過放映式打印在電介質(zhì)層數(shù)的電極層和焊接層制造壓制品。按常規(guī)，AgPd作為電極材料，BaTiO3作為陶瓷的電介質(zhì)使用。 2000年以前， MLCs市場在與通信的指數(shù)發(fā)展的步幅增長。 他們生產(chǎn)電容范圍在10 F (通常范圍Ta和Al電解電容); 他們?cè)诟哳l

80、率應(yīng)用上是非常有用的。從歷史上看，陶瓷電容器是一種雙端非極性設(shè)備。經(jīng)典陶瓷電容器是圓盤電容器。這個(gè)設(shè)備把晶體管的使用日期提早，廣泛地使用了在真空管設(shè)備(即無線電接收機(jī))。從1930，經(jīng)過20世紀(jì)50年代和20世紀(jì)50年代的分離晶體管設(shè)備到20世紀(jì)80年代。在2007年，陶瓷圓盤電容器在電子設(shè)備的普遍使用，它提供高容量和小尺寸，在同類中有很高的性價(jià)比。</p><p>　　其他發(fā)現(xiàn)了的采用陶瓷材料，使用了的其他陶瓷

81、材料的是CaZrO3、MgTiO3， SrTiO3等。一個(gè)典型10 F MLC是 (3.2 x 1.6 x 1.5 mm) 大小的芯片。Mn、Ca、Pd，Ag等使用的是某些其他內(nèi)部電極?；诰€性電介質(zhì)已開發(fā)出高壓電容器磁盤。這些層較薄的MLCs與其適用是因?yàn)樗麄兊母邚?qiáng)制性領(lǐng)域。 其中一個(gè)關(guān)鍵是材料加工。要注意同類混合在泥漿的添加劑的參數(shù)。粘結(jié)劑分布在綠色陶瓷上，表面程度粗糙，尺寸精細(xì)，鎳粉綠色，廣告片堆積沉積等工藝技術(shù)發(fā)揮了至關(guān)重要的研

82、究作用。任何一個(gè)這些事實(shí)，如果處理不當(dāng)，會(huì)導(dǎo)致設(shè)備的失敗。例如，提供5 m厚實(shí)的綠色板料roughess，給0.5m是必須的，以便與內(nèi)在鎳電極的一個(gè)光滑的接觸面可以建立。這是一個(gè)電場非常重要的因素，避免濃度，波峰，其中充電電極的排放，加速，故障會(huì)導(dǎo)致短路或失敗。常規(guī)板料或打印方法有有一個(gè)技術(shù)極限在1 m電介質(zhì)附近; 為了進(jìn)一步減少厚度，可以使用如，化學(xué)氣相沉積，濺射薄膜技術(shù)，等離子噴涂等。</p><p>　　其

83、他類型的電容器是使用稀薄的聚酯薄膜，使用薄的聚酯薄膜和聚丙烯薄膜作為電介質(zhì)和元釉電容器的電極板納入了真空蒸鍍薄膜與金屬，如鋁。薄片可以是聚酯，聚丙烯或聚碳酸酯作。此外電容指定取決于介質(zhì)使用，例如聚酯薄膜電容器，聚丙烯電容器，云母電容器，金屬化聚酯薄膜電容器等。</p><p><b>　　4. 雙層電容器</b></p><p>　　Electric/electroc

84、hemical雙層電容器(EDLC)是獨(dú)特的電子存貯設(shè)備，比常規(guī)電容器比電池可能存放更多能量和提供更大的功率密度。 即EDLCs從太陽或風(fēng)能填補(bǔ)電池和常規(guī)電容器之間的空白，允許對(duì)各種各樣的力量和能量需要，備用電源的申請(qǐng)電子設(shè)備的，裝載成水平，引擎混合車和引起的電存貯的開始或者加速度。 EDLC運(yùn)作根據(jù)雙重層數(shù)電容的原則在電荷在電極表面被積累的電極或電解質(zhì)接口，并且安排相反充電離子在電解質(zhì)邊。</p><p>　　

85、圖2.一個(gè)EDLC細(xì)胞的電荷存儲(chǔ)機(jī)制在懶惰和被充電的情況下 </p><p>　　圖2顯示電荷存儲(chǔ)機(jī)制在EDLC細(xì)胞和圖3的顯示一個(gè)典型的EDLC細(xì)胞的配置。 有雙層電容器的二種主要類型，如，由電荷存儲(chǔ)機(jī)制分類： (1)電子雙重層數(shù)電容器; (ii)電化學(xué)雙層電容器或超級(jí)或者偽電容器。 EDLC在雙重層數(shù)存放能量在電極或電解質(zhì)接口，而超級(jí)電容器承受在電極和電解質(zhì)之間的感應(yīng)電流的反應(yīng)在一個(gè)適當(dāng)?shù)臐撛诘拇翱诶铩?因

86、而為細(xì)胞的建筑用于的電極材料前的主要是碳材料，當(dāng)為后者時(shí)，電極材料包括過渡碳金屬氧化物或混合物和金屬氧化物或者聚合物。電解質(zhì)可以是含水或非水的根據(jù)EDLC細(xì)胞的建筑方式。</p><p>　　圖3.典型的配置EDLC細(xì)胞 </p><p>　　有兩個(gè)值得關(guān)注的大方向。 一個(gè)是長遠(yuǎn)的發(fā)展目標(biāo)：電力推進(jìn)車輛，而另一種是：與最大能量內(nèi)含的電源和最低的可能的大小和重量便攜式的電子設(shè)備的迅速增長。

87、</p><p><b>　　5.結(jié)論</b></p><p>　　據(jù)蒙大拿州市場調(diào)查，超級(jí)電容器正在成為一個(gè)在鐵路車輛制動(dòng)能量儲(chǔ)存有前途的解決手段。鐵路部門的技術(shù)發(fā)展也證明是預(yù)期以外的高度動(dòng)態(tài)的：柴油電動(dòng)車，接觸網(wǎng)的城市輕軌的自由運(yùn)作，啟動(dòng)柴油發(fā)動(dòng)機(jī)，混合動(dòng)力電動(dòng)汽車，工業(yè)應(yīng)用，電梯系統(tǒng)，托盤車等，時(shí)間發(fā)展范圍預(yù)期是未來5到10年。主要發(fā)展目標(biāo)將是：?使用壽命長&

88、lt;/p><p>　　?增加的額定電壓的工作溫度范圍 </p><p>　　?提高對(duì)能源和功率密度·</p><p>　　最近，混合動(dòng)力汽車引入了市場，但它非常昂貴，超出了人的承受范圍。短缺和礦物燃料的成本已經(jīng)激發(fā)了以可行的替代技術(shù)為目的的商業(yè)活動(dòng)。在這種情況下，EDLCs也是有用的從非傳統(tǒng)能源產(chǎn)生的能量的存儲(chǔ)。EDLC供應(yīng)的服務(wù)中心設(shè)定的未來可能是設(shè)立雙電