共軛聚合物半導(dǎo)體的光譜研究.pdf

1、聲明本學(xué)位論文是我在導(dǎo)師的指導(dǎo)下取得的研究成果，盡我所知，在本學(xué)位論文中，除了加以標(biāo)注和致謝的部分外，不包含其他人已經(jīng)發(fā)表或公布過的研究成果，也不包含我為獲得任何教育機(jī)構(gòu)的學(xué)位或?qū)W歷而使用過的材料。與我一同工作的同事對本學(xué)位論文做出的貢獻(xiàn)均已在論文中作了明確的說明。研究生簽名：鋤f占年弓月2o日學(xué)位論文使用授權(quán)聲明南京理工大學(xué)有權(quán)保存本學(xué)位論文的電子和紙質(zhì)文檔，可以借閱或上網(wǎng)公布本學(xué)位論文的部分或全部內(nèi)容，可以向有關(guān)部門或機(jī)構(gòu)送交并授權(quán)

2、其保存、借閱或上網(wǎng)公布本學(xué)位論文的部分或全部內(nèi)容。對于保密論文，按保密的有關(guān)規(guī)定和程序處理。研究生簽名：≥口以年，月2o日壘!墮鱉!一碩士學(xué)位論文______●_●——___—●—_—————●——●_●__________________________________________________—●__—_—_——————，—————————————————————————————————————一T～一一AbstractCon

3、jugatedpolymersemiconductorisallimportantmaterialofproducingorganicsolarcellandorganiclightemissiondiode(OLED)，withhighPLquantumefficiencyandgoodfilmqualityNowadaysthestudyofeonjugatedpolymerhasacquiredgreatprogress，buti

4、tneedsmoreworktostudytheinterchainphotoexcitationsandconjugatedpolymerphotoexcitationsofdifferentchainlengthtodeepentheunderstandingonitsphotophysicsInthiswork，inthefilmandsolutionofthemodelmaterialof2methoxy5(2一ethylhex

5、yloxvlpoly(paraphenylenevinylene)(MENPPV)withvariouschainlengths，wehavemeasuredphotoluminescenceandphotoinducedabsorptionspectroscopytostudytheiropticalpropertieswithwhichwewillanalyzethepropertiesandregulatorymechanismo

6、finterchainexcitedstatesandtheregulatorymechanismInthisthesis，wehavebuiltupasetofmeasurementsystemsforphotoluminescence(PL)andphotoinducedabsorption(HA)spectroscopiesWehavewrittenthecontrolanddatecollectionprogramsusingL

7、abviewforautomaticmeasurementsWemeasuredthetemperaturedependencePLandPIAspectraofMEHPPVfilmwithdifferentchainlengthsatvariousannealingtemperaturesAfteranalyzingtheopticalprocessesfromthespectra，we90tthemainconclusionsasf

8、ollows：①TheannealingCanincreasetheinterchaininteractionsinfilm，byenhancingthedelocalizationof兀一electronsthenfacilitatingtheformationofinterchainexcitedstates；thePLemissionaround680nnlatlowtemperatureisduetointerchainexci

9、mersinsteadofintrachainexcitonsfor450Kannealedfilm；FurthermoretheinterchainphotoexcitationsplaycrucialrolesinthephotophysicsofMEH—PPVfilmsTheftmermeasurementsonPIAspectrumofMEHPPVfilmssuggestthattheinterchainphotoexciati

10、onsarealsoimportantforthegenerationoftripletexcitons@Theincreasingofconjugatedpolymerschainlengthresultsinaggregationofpolymerchain⑧Bydetectingthepolarizationeffectofphotoluminescenceandphotoinducedabsorptionspectrawefen

11、dthatthePLfromsingletexcitonsandexcimersaswellasthePIAfromtripletexcitonsofMEH—PPVhavepolarizationmemoryeffect，whichmayoriginatethenatureofquasionedimensionalcharacteristicsofphotophysicsinconjugatedpolymersKeywords：Conj