有機(jī)雙組分分子晶體的制備、反應(yīng)及應(yīng)用.pdf

1、南開大學(xué)碩士學(xué)位論文有機(jī)雙組分分子晶體的制備、反應(yīng)及應(yīng)用姓名：杜海峰申請(qǐng)學(xué)位級(jí)別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：孟繼本2001.5.1南開大學(xué)碩士研究生畢業(yè)論文英文摘要AbstractThetwocomponentmolecularcrystalsplayatlimportantroleinthesolid—statereactionEspeciallytheyhavegreattheoreticalandpracticalinteres

2、tinthe“absolute”asymmetricsynthesis，asymmetricinductionandresolutionofracemiccompoundsInordertogetmoreinformationontheformationofmolecularcrystalsandtheirchemicalreactivitywestudiedtheirsolidstatephotoreaction，solidstate

3、reductionandtheresolutionofmcemieLl，Bi2naphthanol(BINOL)0urmainfindingsareasfollows：1，Aseriesoftwocomponentmolecularcrystalsformedbetweendifferentdiarylaceficacidsandacridinewerepreparedandtheirsolidstatephotoreactionswe

4、reinvestigatedMoreovertherelationshipsbetweensubstitutentonthebenzeneringandcrystedchirali饑themoleculararrangementpatterninthecrystallatticeandthereactionpathwaywerediscussed2，EspeciallyitWasfoundthatwhenArWas4methoxyphe

5、nylgrouP，opticallyactiveproductWasisolatedItiSasuccessfulexampleof“absolute”asymmetricsynthesisinthesolidstate3，AseriesofmolecularcrystalsformedbetweenarylketoneandenantiopureBINOLwerepreparedandtheirsolidstatereductionw

6、ithsodiumborohydroxideweJeinvestigated4，Reductionoftwo—componentmolecularcrystalformedbetweenenantiopureBINOLandacetylferrocenewithNaBH4gaveopticallyactivecompoundItshowsasymmetricinductionintllesolidstatereductionmaybea

7、ttributedtothechiralmicroenviomentofmolecularcrystal5，AchiralhostcompoundWaspreparedfromLglutamicacidanditwassuccessfullyusedintheresolutionofracBINOLKeywords：twocomponentmolecularcrystal，“absolute”asymmetricsynthesis，as