版權(quán)說(shuō)明:本文檔由用戶提供并上傳,收益歸屬內(nèi)容提供方,若內(nèi)容存在侵權(quán),請(qǐng)進(jìn)行舉報(bào)或認(rèn)領(lǐng)
文檔簡(jiǎn)介
1、五邑大學(xué)本科畢業(yè)設(shè)計(jì) 五邑大學(xué)本科畢業(yè)設(shè)計(jì)(論文 論文)I摘要 摘要本文主要針對(duì)目前市場(chǎng)上仍沒(méi)有綜合性能十分完善的聚氨酯水性涂料, 單純的水性聚氨酯在性能上還不能滿足人們的需求,利用環(huán)氧樹脂出色的粘接能力、高模量、高強(qiáng)度、優(yōu)良的附著力、低收縮率和耐水、耐化學(xué)性好等優(yōu)點(diǎn)以及丙烯酸樹脂較好的耐水性、保色性、物理機(jī)械性能和耐候性能且成本低廉的特點(diǎn), 通過(guò)接枝共聚方式將這兩種樹脂引入水性聚氨酯鏈段中,對(duì)水性聚氨酯進(jìn)行改性。文中通過(guò)以甲苯二異氰酸
2、酯(TDI) 、聚醚多元醇(PPG220) 、二羥甲基丙酸(DMPA)、三羥甲基丙烷(TMP)、 乙二胺(EDA)、 環(huán)氧樹脂 (E-44) 、 2-乙烯氧甲基-2-羥甲基丁醇(TMPME)和丙烯酸 (MMA、 BA、 AA)混合單體等為主要原料,通過(guò)自乳化法合成了以環(huán)氧樹脂(E-44)改性的水性聚氨酯乳液,在環(huán)氧樹脂改性水性聚氨酯的基礎(chǔ)上,利用丙烯酸酯進(jìn)一步改性。最終得到性能優(yōu)良的改性聚氨酯乳液。 研究了多個(gè)化學(xué)組分對(duì)乳液粘度、穩(wěn)定性
3、的影響以及對(duì)膜機(jī)械性能、耐介質(zhì)性能的影響。關(guān)鍵詞:水性聚氨酯;改性;丙烯酸酯;環(huán)氧樹脂五邑大學(xué)本科畢業(yè)設(shè)計(jì) 五邑大學(xué)本科畢業(yè)設(shè)計(jì)(論文 論文)III目錄摘要·······················
4、3;····································
5、183;····································
6、················IAbstract···················&
7、#183;····································
8、;····································
9、83;···············II第一章 緒論····················
10、;····································
11、83;····································&
12、#183;········11.1 概述··························
13、3;····································
14、183;····································
15、··11.2 國(guó)內(nèi)外概況·································
16、····································
17、3;·······················11.3 水性聚氨酯的分類···········&
18、#183;····································
19、;··································· 21.4 水性聚
20、氨酯的制備方法···································
21、83;····································&
22、#183;···· 21.4.1 外乳化法······························
23、;····································
24、83;····················· 21.4.2 自乳化法·············&
25、#183;····································
26、;····································
27、83;· 21.4.2.1 丙酮法·································
28、····································
29、3;············· 31.4.2.2 預(yù)聚體分散法····················
30、3;····································
31、183;················ 31.4.2.3 熔體分散縮合法·················&
32、#183;····································
33、;················· 31.4.2.4 酮亞胺—酮連氮法················
34、83;····································&
35、#183;·············· 31.4.2.5 封端-NCO 基團(tuán)法··················
36、83;····································&
37、#183;············· 41.5 水性聚氨酯的改性····················
38、83;····································&
39、#183;························· 41.5.1 物理共混·········
40、;····································
41、83;····································&
42、#183;····· 41.5.2 化學(xué)接枝共聚····························
43、83;····································&
44、#183;················41.5.2.1 環(huán)氧樹脂改性·················
45、183;····································
46、···················· 51.5.2.2 丙烯酸酯(PA)改性·············
47、183;····································
48、···············51.5.2.3 聚硅氧烷改性···················&
49、#183;····································
50、;·················· 61.5.2.4 蓖麻油改性················
51、····································
52、3;························ 61.5.2.5 其他改性方法·········
53、3;····································
54、183;··························· 71.6 制備環(huán)氧樹脂—丙烯酸酯改性水性聚氨酯乳液的物料····&
55、#183;·································71.6.1 多異氰酸酯·
56、;····································
57、83;····································&
58、#183;·········· 71.6.2 多元醇························
59、····································
60、3;······························ 71.6.3 催化劑····
61、83;····································&
62、#183;····································
63、;············· 71.6.4 親水性擴(kuò)鏈劑·····················&
64、#183;····································
65、;························71.6.5 交聯(lián)劑···········
66、;····································
67、83;····································&
68、#183;······ 81.6.6 成鹽劑····························
69、····································
70、3;·························· 81.6.7 擴(kuò)鏈劑········
71、83;····································&
72、#183;····································
73、;········· 81.6.8 溶劑··························
74、;····································
75、83;······························· 81.6.9 水···
76、3;····································
77、183;····································
78、···················· 81.6.10 改性劑··············
79、3;····································
80、183;····································
溫馨提示
- 1. 本站所有資源如無(wú)特殊說(shuō)明,都需要本地電腦安裝OFFICE2007和PDF閱讀器。圖紙軟件為CAD,CAXA,PROE,UG,SolidWorks等.壓縮文件請(qǐng)下載最新的WinRAR軟件解壓。
- 2. 本站的文檔不包含任何第三方提供的附件圖紙等,如果需要附件,請(qǐng)聯(lián)系上傳者。文件的所有權(quán)益歸上傳用戶所有。
- 3. 本站RAR壓縮包中若帶圖紙,網(wǎng)頁(yè)內(nèi)容里面會(huì)有圖紙預(yù)覽,若沒(méi)有圖紙預(yù)覽就沒(méi)有圖紙。
- 4. 未經(jīng)權(quán)益所有人同意不得將文件中的內(nèi)容挪作商業(yè)或盈利用途。
- 5. 眾賞文庫(kù)僅提供信息存儲(chǔ)空間,僅對(duì)用戶上傳內(nèi)容的表現(xiàn)方式做保護(hù)處理,對(duì)用戶上傳分享的文檔內(nèi)容本身不做任何修改或編輯,并不能對(duì)任何下載內(nèi)容負(fù)責(zé)。
- 6. 下載文件中如有侵權(quán)或不適當(dāng)內(nèi)容,請(qǐng)與我們聯(lián)系,我們立即糾正。
- 7. 本站不保證下載資源的準(zhǔn)確性、安全性和完整性, 同時(shí)也不承擔(dān)用戶因使用這些下載資源對(duì)自己和他人造成任何形式的傷害或損失。
最新文檔
- 環(huán)氧樹脂改性聚氨酯-丙烯酸酯乳液的合成研究.pdf
- 聚氨酯-環(huán)氧樹脂-丙烯酸酯
- 水性聚氨酯—丙烯酸酯復(fù)合乳液的制備及其改性研究.pdf
- 丙烯酸酯改性水性聚氨酯乳液的合成研究.pdf
- 丙烯酸酯改性水性聚氨酯乳液的制備與性能研究.pdf
- 丙烯酸酯改性水性聚氨酯.pdf
- 水性丙烯酸酯改性聚氨酯共聚乳液的制備及性能研究.pdf
- 丙烯酸酯與水性聚氨酯復(fù)合乳液的制備.pdf
- 水性聚氨酯乳液的制備及其與丙烯酸酯交聯(lián)改性的研究.pdf
- 丙烯酸酯改性水性聚氨酯復(fù)合乳液的合成研究.pdf
- UV固化水性聚氨酯丙烯酸酯樹脂.pdf
- 水性聚氨酯丙烯酸酯復(fù)合乳液的合成及其改性研究.pdf
- 水性聚氨酯及其丙烯酸酯改性的研究.pdf
- 含氟丙烯酸酯改性水性聚氨酯.pdf
- 丙烯酸酯乳液、聚氨酯乳液的制備及性能研究.pdf
- 聚氨酯改性丙烯酸酯抗菌乳液的制備及性能研究.pdf
- 新型丙烯酸酯改性聚氨酯水性樹脂的合成與性能研究.pdf
- 聚氨酯-聚丙烯酸酯復(fù)合乳液的制備及其改性研究.pdf
- 環(huán)氧樹脂-聚丙烯酸酯復(fù)合乳液的制備和表征.pdf
- 水性聚氨酯丙烯酸酯復(fù)合乳液合成及性能研究.pdf
評(píng)論
0/150
提交評(píng)論